Partial Crystallization Behavior of Iron Based Glass-Coated Amorphous Metal
dc.contributor.author | Conklin, Morgan D. | |
dc.date.accessioned | 2011-10-21T19:45:12Z | |
dc.date.available | 2011-10-21T19:45:12Z | |
dc.date.issued | 2004 | |
dc.description.abstract | Thermal and physical properties of glass-coated amorphous metal fibers have been investigated. It is demonstrated that an amorphous metal having a composition of Fe_{77.5}Si_{7.5}B_{15} undergoes a two-stage crystallization process when heated, and that the lower temperature crystallization can be completed without the higher temperature crystallization occurring. Scanning electron microscopy shows that such “Partial- Crystallization” creates a nanocrystalline, apparently interconnected structure within an amorphous matrix. The activation energy for the lower and upper temperature crystallizations have been calculated to be approximately 424 kJ/mol and 361 kJ/mol, respectively, using differential scanning calorimetry and Kissinger’s analysis. Crystallization temperature is heating rate dependant; at 10 ºC per minute, the two crystallizations occur at 540.5ºC and 550.5ºC respectively. Using a programmable dental furnace, a sample can be subjected to a heating curve and quenched in air, causing only the first crystallization to occur. The material so prepared is shown to have properties distinguished from the as-received material. The ultimate tensile strength of a partially crystallized fiber is measured to be 10-40% weaker than that of an as received sample. A core composition of Co_{68.15}Fe_{4.35}Si_{12.5}B_{16} has also been tested and has a single crystallization temperature (at 10ºC/min) of 552ºC with an activation energy of 503 kJ/mol. Using thermo-magneto-gravimetric analysis, Curie temperatures have been measured for the amorphous metal compositions; 426ºC for Fe_{77.5}Si_{7.5}B_{15}, and 319ºC for Co_{68.15}Fe_{4.35}Si_{12.5}B_{16}. | en_US |
dc.identifier.uri | http://hdl.handle.net/10829/304 | |
dc.language.iso | en-US | en_US |
dc.publisher | Alfred University. Faculty of Ceramic Engineering. Kazuo Inamori School of Engineering | en_US |
dc.subject | Coatings | en_US |
dc.subject | Crystallization | en_US |
dc.subject | Differential scanning | en_US |
dc.subject | SEM analysis | en_US |
dc.subject | Porous glasses | en_US |
dc.subject | Iron | en_US |
dc.subject | Amorphous metals | en_US |
dc.title | Partial Crystallization Behavior of Iron Based Glass-Coated Amorphous Metal | en_US |
dc.type | Thesis | en_US |
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